Annealing PLA in powdered salt using sous vide

andrewmemoryblog@gmail.com (Andrew's Memory Blog) — Sat, 31 Oct 2020 03:53:26 -0700

Stefan of CNC Kitchen recently posted about annealing (and later re-melting) PLA prints to improve their strength and temperature resistance. I decided to do some experiments of my own.

My method was to print out some PLA objects, pack them in a salt powder that gets vacuum-sealed, and then toss that in the sous vide for 18 hours. The sous vide doesn’t get hot enough to re-melt PLA, so it doesn’t have exactly the same characteristics, but it does gain some benefit. The advantage to the sous vide method is that it’s more available than a constant-temperature oven.

I did informal tests on the annealed prints for a few characteristics:

Smoothing - did the texture of the print change?
Strength between layers - was the print any stronger between layers?
Waterproofing - did the print eventually get waterlogged when placed in water?
Temperature resistance - did the print get as flexible when subjected to increased temperatures as a non-annealed print?

Procedure
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I used four objects: a hollow spheroid, a 30x5x5 mm bar, a calibration cube, and a box with tabs that were oriented perpendicular to the layers. I ground up plain (uniodized) salt in a spice mill, and put that into a FoodSaver bag that was double-sealed at the bottom. Relative humidity when I sealed the bag was around 33%.

I nestled my prints in the salt, then vacuum-sealed the bag and double-sealed the top.

Sealed in the bag. The salt prevented sharp edges from poking holes.

Next, I tossed the bag in a pot of water along with an Anova Nano sous vide stick. I set the temperature for 80 C (176 F) and left it that way for 18 hours.

Cooking at 80 C

After that, I turned the sous vide stick off and let the pot come to room temperature.

Observations
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When I removed the salt from the bag, it had formed a solid mass that could be broken apart by hand. I carefully extracted the printed objects. The box lid and letters on the calibration cube letters were packed with salt, but that could be washed out easily.

I measured most of the objects, and found that they had indeed changed size - all were a few percent smaller than before annealing. So I knew annealing did something:

Print	Original dimension (mm)	After annealing (mm)	Change (as % of original)
Calibration cube X	20.13	19.98	99.3
Calibration cube Y	20.08	19.89	99.1
Calibration cube Z	20.15	19.98	99.2
Spheroid diameter	20.08	19.78	98.5
Spheroid height (Z)	24.82	24.72	99.6
Bar length (X)	30.23	30.06	99.4
Bar width (Y)	5.14	5.06	98.4
Bar height (Z)	5.00	4.95	99.0

Results
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Tabs broke off just as easily after annealing

Smoothing: unlike Stefan’s experiments with PLA re-melting, the annealed objects did not change texture. The plastic still showed the same layer lines and other 3D printer artifacts that non-annealed prints did. I attribute that to the fact that the plastic never flowed - the annealing temperature was always below the melting point.
Strength: when I assembled the box, the tabs broke off exactly as they had when I printed non-annealed PLA using the “wrong” orientation. I couldn’t measure it, but I don’t think annealed PLA was any stronger between layers.
Waterproofing: after immersing the spheroid in water for a week, it seemed to sink a little lower, but then stop. I don’t think I’d want to claim that annealing changed the waterproofing of the prints.
Temperature resistance: this did appear to change. I put both the annealed and non-annealed bar prints on the printer bed at 73 C (163 F). After a few minutes, the non-annealed bar was flexible enough that it could be bent between my fingers. In contrast, the annealed print remained solid, and in fact snapped when I applied more pressure.

The non-annealed part was flexible after heating to 73 C. The annealed part was not.

Conclusion
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Annealing sous vide is useful for imparting temperature resistance to PLA, and may be a valuable technique for PLA objects that need to live in a hot environment (such as a car in the summertime). Sous vide annealing is easier and more reliable than trying to anneal in a kitchen oven. Annealing alone does not change texture, strength between layers or waterproofing characteristics.

3d-Printing on Andrew's Memory Blog

Annealing PLA in powdered salt using sous vide

Procedure #

Observations #

Results #

Conclusion #

Procedure
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Observations
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Results
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Conclusion
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